Charleroi is a city and a municipality of Wallonia, located in the province of Hainaut, Belgium. The city is situated in the valley of the Sambre, in the south-west of Belgium, not far from the border with France. By 1 January 2008, the total population of Charleroi was 201,593. The metropolitan area, including the outer commuter zone, covers an area of 1462 km² with a total population of 522,522 by 1 January 2008, ranking it as the 5th most populous in Belgium after Brussels, Antwerp, Liège, and Ghent. The inhabitants are called Carolorégiens or simply Carolos.