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From Union Station Rail train to Kipling Station, line 192 bus to Toronto airport, fly to Valencia airport, then line 5 Metro to Valência. 13hrs 46min $665. From Toronto Island airport fly to Valencia airport then line 5 Metro to Valência. 14hrs 08min $657. From Union Station Rail train to Kipling Station, line 192 bus to Toronto airport, fly to Madrid airport, train to Madrid-Puerta de Atocha, then train to Valência. 13hrs 29min $592. From Union Station Rail train to Kipling Station, line 192 bus to Toronto airport, fly to Barcelona airport, train to Barcelona Sants, then train to Valência. 15hrs 00min $561.