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From Siena bus to Pisa Centrale then train to La Spezia Centrale. 2hrs 38min 56 €. From Siena train to Empoli, train to Pisa Centrale, then train to La Spezia Centrale. 3hrs 00min 41 €. From Siena line 145 bus to Pisa Airport, bus to Pietrasanta, then train to La Spezia Centrale. 6hrs 16min 27 €. From Siena drive to La Spezia. 2hrs 38min 37 €.